Quick answer: no — Washington does not let a surviving spouse add their late spouse's unused exclusion to their own, unlike federal law. Run your own numbers in the Washington estate tax calculator.
No portability, confirmed directly
The marital deduction still defers the tax
The unlimited marital deduction lets assets pass to a surviving spouse free of Washington estate tax at the first death. It's a real, working deduction — it just defers the tax to the second death rather than eliminating it, since Washington gives the surviving spouse no extra exclusion to offset what's now a larger combined estate.
Why this catches couples off guard
Everything sheltered by the marital deduction at the first spouse's death becomes fully exposed at the second spouse's death, with only one $3,000,000 exclusion left to work with — not two. A couple who simply left everything to each other, assuming it would "average out," can end up with a much larger taxable estate than either spouse had individually.
The standard workaround: a credit-shelter trust
Many Washington couples use a credit-shelter (bypass) trust at the first spouse's death, which uses that spouse's own exclusion immediately rather than relying on a portability election the state doesn't offer — effectively recreating, through trust planning, what portability would have done automatically at the federal level.
A local probate attorney can review your estate — many offer a free consultation.
This is a state-specific planning gap, separate from federal portability, which Washington's own tax simply doesn't recognize.